Experience has shown that stainless steels can suffer from hydrogen induced stress cracking hisc under cathodic protection in seawater. Hydrogen embrittlement also known as hydrogen assisted cracking and hydrogeninduced cracking, describes the embrittling of metal after being exposed to hydrogen. Hydrogen induced cracking of subsea duplex stainless steel. Hydrogeninduced cracking is also known as cold cracking, delayed cracking or underbead cracking. Sulfide stress cracking ssc is a type of hydrogen cracking which presents a cathodic embrittlement mechanism. Hydrogen assisted stress corrosion corrosion cracking is a separate type of scc, which is principally different from the stress corrosion cracking undergoing by anodic dissolution. Hydrogen stress cracking occurs when corrosion from acids like wet hydrogen sulfide or hydrofluoric acid hf cause atomic hydrogen to penetrate hardened or higher strength steels and cause stress cracking. Environmental cracking is a broad term that includes corrosion fatigue, hightemperature hydrogen attack, hydrogen blistering, hydrogen embrittlement, liquid metal embrittlement, season cracking, caustic embrittlement, stress corrosion cracking, stepwise cracking, sulfide corrosion cracking and sulfide stress cracking. The first type is commonly referred to as hydrogen induced cracking hic and can occur where little or no applied or residual tensile stress exists.
The pressure created from the buildup can further elevate, which makes metal lose its tensile strength and ductility, reaching the point of cracking, or hic. The path of crack growth in hydrogen embrittled steels is a function of the stress intensity factor, k mpavm. Cathodic hydrogen absorption cha is a subset of scc. If stress induces cracking under these conditions, the path is transgranular. Sulfide stress corrosion cracking occurs in presence of hydrogen sulfide.
Susceptibility to hydrogen induced cracking of api 5l b and x52ms lowcarbon steels in nace 177a, 177b, and 284b solutions has been investigated by the present work. Unstressed test specimens are exposed to a solution at temperature of 25deg cent with continuous h2s gas flow. Despite extensive study, much remains to be learned about the phenomena. The hydrogen atom is the smallest of all atoms and hydrogen attack is similarly insidious and hidden from simple inspection techniques. Jun 27, 2019 the components showed a single longitudinal crack along the swaged ferrule, which arrested towards its thicker section. But there are several other types, such as liquidmetal embrittlement, that we must understand as well. The cracks are usually nonbranching and fast growing, and are more often transgranular through the grains rather than intergranular through the grain boundaries.
Stressoriented hydrogeninduced cracking an overview. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. Hic testing is recommended to evaluate the resistance of pipeline and pressure vessel plate steels to hydrogen induced cracking corrosion caused by hydrogen absorption from aqueous sulfide corrosion. Astm f519 hydrogen embrittlement he testing element.
Thereby the pickup of hydrogen at a steel surface subject to corrosion that. Damage due to hydrogen embrittlement and stress corrosion. Inherent stress arising from the manufacturing process or induced stress arising from incorrect installation. It involves the ingress of hydrogen into a component, an event that can seriously reduce the ductility and loadbearing capacity, cause cracking and catastrophic brittle failures at stresses below the yield stress of susceptible materials. Hydrogen stress cracking is a form of hydrogen embrittlement that occurs when corrosion from acids like wet hydrogen sulfide and hydrofluoric acid cause. Hydrogen induced craking hic, also referred to as hydrogen stress cracking or static fatigue, is a typical form of hydrogen embrittlement. Mechanisms that have been proposed to explain embrittlement include the formation of brittle hydrides, the creation of voids that can lead to bubbles and pressure buildup within a material and e. Because stress corrosion cracks frequently initiate at pits, and pits. Hic test, hydrogen induced cracking test, step wise cracking. Hydrogeninduced cracking hic is still a challenging issue that requires. Cracking design and material a number of failures of subsea production equipment made from corrosion resistant alloys cra duplex and martensitic caught the attention of the offshore industry 510 years ago. The movement of mobile atomic hydrogen through steel, known as hydrogen permeation, is a prerequisite for most types of hydrogen damage, including hydrogen induced cracking hic, stress oriented hydrogen induced cracking sohic and.
A metallographic analysis of these steels was performed before and after nace tm0284 standard testing. There are several types of stress corrosion cracking scc, for example, chlorideinduced scc and h 2 sinduced scc. Natta, piazza leonardo da vinci 32, 203 milano, italy. This is a type of deterioration which can be linked to corrosion and corrosion control processes. Another type of hydrogen corrosion, stress orientated hydrogen induced cracking sochic, is normally found in the base metal adjacent to the weld, where the stress point is highest due to the internal pressure of the. It is characterized by the brittle fracture of a normally ductile alloy under sustained load in the presence of hydrogen. Stress corrosion cracking and hydrogen embrittlement of. Processes or conditions involving wet hydrogen sulfide, i.
Most heat treaters are aware of many failure phenomena, perhaps the most wellknown of which is hydrogen embrittlement aka hydrogen assisted cracking. Susceptibility to hydrogen blistering and hydrogen induced cracking can be apportioned to the quality of the steel plate used. The role of hydrogen in the mechanism of stress corrosion cracking has been known since the 1970s so that preventative measures have since been introduced. May 07, 2019 sulfide stress corrosion cracking occurs in presence of hydrogen sulfide. Stress corrosion cracking stress corrosion cracking scc is a known condition, which can sometimes occur when certain conditions are met and occurring simultaneously. Strength effect in stress corrosion cracking of high. Abstract hydrogen induced cracking hic has been studied phenomenologically.
This equation was also applicable to scc of the highstrength steel in aqueous solution. Hydrogen induced cracking is also known as cold cracking, delayed cracking or underbead cracking. For more information about how we perform hydrogen induced corrosion hic testing, or to request a quote. Heatrecovery steam generators hrsgs that have 300 series ss feedwater heaters may suffer chloride induced stress corrosion cracking from the gas side od when the temperature of the inlet water is below the dewpoint of hydrochloric acid. Maybe you can find chlorides in the cracks by electron microscopy. Hydrogen induced stress cracking of duplex stainless steel subsea. Pdf sulfide stress corrosion cracking and hydrogen induced. Hydrogen induced stress cracking hisc and dnvrpf112. Cracks can develop by both transgranular and intergranular paths. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. Unstressed test specimens are exposed to a solution at temperature of. This penetration can lead to the brittle fracture of materials that are normally ductile when hydrogen happens to be present in their environment.
Unfortunately, while this technique is useful and intended to prevent structural carbonsteel components from seawater corrosion, it can introduce atomic hydrogen to the dss components attached to the structural carbon steels, which are known to be susceptible to hydrogen embrittlement via hydrogen induced stress cracking hisc. It involves atomic hydrogen, which is the smallest atom, that diffuses into a metallic structure. Hydrogen may be produced by corrosion reactions such as rusting, cathodic. Woollin p and murphy w, hydrogen embrittlement stress cracking of superduplex stainless steel, proc conf corrosion 2001, nace international, paper 01018. Hydrogen induced stress cracking hisc rolled alloys, inc. When steel is embrittled and fails by cracking due to exposure to hydrogen in the presence of stress, the failure mechanism is known as hydrogen induced stress corrosion cracking hiscc 3. Hydrogen induced stress cracking hisc resistance and. Element carries out sohic testing to nace mr0175iso 15156 using test methods in bs 8701 full ring test, nace tm0177method a tensile or nace tm0316 four point bend. This can occur during elevatedtemperature thermal treatments and in service during electroplating, contact with maintenance chemicals, wet h2s, corrosion reactions, cathodic protection, and operating in highpressure hydrogencontaining environments. The effect of microstructure on hic is discussed for steels having two different levels of nonmetallic inclusions.
A model has been developed which simulates the deformation of single crystal austenitic stainless steels and captures the effects of hydrogen on stress corrosion cracking. The hydrogenation reactors i know were all made from ferritic materials fullfilling the api 941 conditions and having a pwht for protection against hydrogen induced cracking. Hydrogen induced cracking hic is a common form of wet h2s cracking caused by the blistering of a metal due to a high concentration of hydrogen. The tests are normally carried out according to nace tm0284.
The components showed a single longitudinal crack along the swaged ferrule, which arrested towards its thicker section. It is more severe than hic as it dramatically diminishes load carrying capabilities of materials. Stress corrosion cracking international institute of. Induced cracking and sulfide stress cracking uhlig. Also high strength structural steels which are welded are exposed to a certain hydrogen pickup which means a risk at fracture and blistering due to hic. Pdf stress corrosion cracking and hydrogen cracking. Hydrogen induced cracking failures of sour gas processing equipment and transmission pipelines have been reported at facilities in libya, saudi arabia and other middleeastern plants. The results showed that the failure developed from a combination of factors, typical for hydrogen induced stress cracking. Galvanically induced hydrogen stress cracking ghsc the presence of hydrogen introduced via corrosion in a metal may result in reduced ductility and increased susceptibility to cracking in the presence of tensile stress applied and or residual. A comparative study of hydrogeninduced cracking resistances. Politecnico di milano, department of chemistry, materials, and chemical engineering g.
Hydrogen induced cracking hic from advanced ndt solutions. Stress corrosion cracking and hydrogen cracking are two important forms of environmental cracking which can cause serious failures in the oil and gas, pipeline, process and many other industries. Corrosion products were characterized by scanning electron microscopy and xray dispersive energy spectrometry, which were. Metallurgical factors in stress corrosion cracking scc and. Stress corrosion cracking scc is a localised corrosion process that can be very damaging in many specific materialsolution systems. Sulfide stress corrosion cracking and hydrogen induced cracking of a216wcc wellhead flow control valve body article pdf available in case studies in engineering failure analysis. Hic usually occurs due to the effects of aqueous hydrogen charging of steel in wet h2s refinery process environments. Hydrogen induced plasticity in stress corrosion cracking of. Stress corrosion cracking and hydrogen embrittlement of high. It is a complex process that is not completely understood because of the variety and complexity of mechanisms that can lead to embrittlement. Hydrogen induced stress cracking hisc resistance and improvement.
A small number of duplex and superduplex stainless steel components have failed in subsea service due to hydrogen induced stress cracking hisc. Corrosionpedia what is sulfide stress cracking ssc. Hydrogen induced cracking hiccauses and prevention. Stress corrosion cracking the international institute of. Stress corrosion cracking scc failure under service of high.
Stress corrosion cracking scc is characterized by cracks propagating either transgranularly or intergranularly along grain boundaries. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Stress oriented hydrogen induced cracking sohic stress orientated hydrogen induced cracking occurs in the area of grain enlargement in weld heat affected zones. Metallurgical factors in stress corrosion cracking scc springerlink.
Hydrogeninduced cracking results from atomic hydrogen being absorbed by solid metals. Hydrogeninduced cracking an overview sciencedirect topics. Corrosionpedia what is hydrogeninduced cracking hic. Hydrogen stress cracking is a form of hydrogen embrittlement that occurs when corrosion from acids like wet hydrogen sulfide and hydrofluoric acid cause atomic hydrogen to penetrate hardened or higher strength steels and cause stress cracking. Fundamentals of hydrogen induced stress cracking in duplex. Unfortunately, the term hydrogeninduced cracking, usually abbreviated as hic, has been introduced to designate cracking sometimes encountered in pipelines or vessels as a result of hydrogen picked up in. The cracking of martensitic and precipitation hardened steel alloys is believed to be a form of hydrogen stress corrosion cracking that results from the entry into the metal of a portion of the atomic hydrogen that is produced in the following corrosion reaction.
Hydrogen induced cracking hic damage is a degradation mechanism active in the oil and gas industry. Hydrogen induced cracking hic is a common form of wet h2s cracking. Damage of metals due to the influence of hydrogen and to stress corrosion cracking is quite frequent and leads to dangerous failures as well as to loss of property and large compensational. Hydrogen induced damage can reveal fracture surfaces that cannot be easily distinguished from cleavage fractures. Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogen induced cracking hic, describes the embrittling of metal after being exposed to hydrogen. It is known that certain metals when exposed to other metals in the liquid or solid state are susceptible to a. It is a form of hydrogen related cracking and can have two distinct morphologies. Hydrogen induced stress cracking of swaged super duplex stainless steel subsea components, corrosion. The ssc of medium strength steels has been a continuing source of trouble in the oil fields, and from these troubles has evolved in international standards 6. So i think the conclusion of the inspection companies is probably right.
Hic test, hydrogen induced cracking test, step wise. The blistering damage tends to form parallel to the surface and to the direction of hoop stress. The scc cracks are those cracks which are induced due to the combined e. Aug 01, 2019 the results showed that the failure developed from a combination of factors, typical for hydrogen induced stress cracking. Unfortunately, the term hydrogen induced cracking, usually abbreviated as hic, has been introduced to designate cracking sometimes encountered in pipelines or vessels as a result of hydrogen picked up in. Hisc hydrogen induced stress considerations 1 day course. Liquidmetal embrittlement 20200408 industrial heating. Hydrogen induced cracking steel features, applications. Stress oriented hydrogen induced cracking sohic consists of blister cracks connected through the thickness direction by transgranular cleavage cracks. This type of failure is known as stress corrosion cracking, often abbreviated to scc. The movement of mobile atomic hydrogen through steel, known as hydrogen permeation, is a prerequisite for most types of hydrogen damage, including hydrogen induced cracking hic, stress oriented hydrogen induced cracking sohic and disbonding. Hydrogeninduced stress cracking of swaged super duplex.
This term should not be confused with stress corrosion cracking scs, since this is anodic in nature. The brittle nature of the fracture surface, calcareous deposits on the ferrule and exposure to cathodic protection suggested hydrogen induced stress cracking hisc. Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogeninduced cracking hic. In contrast to anodic dissolution mechanism hydrogen assisted cracking is enhanced by cathodic reaction. A recent subsea failure of two subsea connectors made of uns s32760, a 25 wt% cr super duplex stainless steel, led to an extensive root cause failure analysis. Mar 28, 2011 weishan huang, jingli luo, hani henein and josiah jordan, sulfide stress cracking assessment of lowalloy l80 casing steel in h 2 s environment, anti corrosion methods and materials, 10. The measured hydrogen content in parts of the material exceeded 40 ppm, more than an order of magnitude higher than what is normally expected in super duplex stainless steels. Dec 19, 2019 sulfide stress cracking ssc is a type of hydrogen cracking which presents a cathodic embrittlement mechanism.
Hydrogen induced stress cracking of swaged super duplex. A recent subsea failure of two subsea connectors made of uns s32760, a 25 wt% cr super duplex. Intergranular cleavage fractures are often difficult to distinguish from cracks that have been formed by intergranular stress corrosion cracking. Effect of microstructure on hydrogeninduced cracking of. Stress oriented hydrogen induced cracking sohic test method. The poorly understood failure mechanisms are difficult to differ entiate, especially in the field. Webcorr provides corrosion consultancy services, corrosion expert witness and corrosion short courses for inhouse training, online and distance learning. Hydrogeninduced cracking hic in steel is a risk problem when steels are charged with hydrogen in service as in various hydrogen sulfide environments like sour oil and gas wells and some power plants. Gas phase water needs to be there as well even in a trace amount. The measured hydrogen content in parts of the material exceeded 40 ppm, more than an order of magnitude higher than what. When such hydrogen atoms combine again in very small metal voids to build molecules of hydrogen, they produce pressure within the cavity. Woollin p and gregori a, avoiding hydrogen embrittlement stress cracking of ferritic austenitic stainless steels under cathodic protection, proc conf omae 2004, paper 51203. The significance of these failures has led to research to define critical loading conditions for hisc, to allow confident design of components in future. The failures were linked to hydrogen embrittlement under stress, also called hisc.
Metallurgical, mechanical and load conditions susceptibility of steel to hi. Hydrogeninduced cracking hic refers to the internal cracks brought about by material trapped in budding hydrogen atoms. Jun 03, 2018 hydrogeninduced cracking hic refers to the internal cracks brought about by material trapped in budding hydrogen atoms. Pdf sulfide stress corrosion cracking and hydrogen. The threshold stress intensity of hydrogen induced cracking k ih during dynamical charging for 40crmo steel decreased linearly with the logarithm of the concentration of diffusible hydrogen, c 0 i. Hydrogen embrittlement and stress corrosion cracking. In one of my client facilities, we have observed cracks and leaks in 2 new hydrogenation reactors moc ss 316l after very few batches induced stress corrosion although none of the raw materials used during operations contain any chloride confirmed by testing. Hydrogen induced cracking of subsea duplex stainless steel twi. Modelling hydrogen induced stress corrosion cracking in.
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